| 1956 | La bohème | Puccini; Victoria de los Ángeles, Jussi Björling, Amara, Merrill, Reardon, Tozzi, RCA Victor Chorus & Orchestra, Sir Thomas Beecham | 10 |
| 1958 | Lucia di Lammermoor | Donizetti; Peters, Peerce, Tozzi, Maero, Rome Opera House Orchestra and Chorus, Leinsdorf | 2 |
| 1959 | Il trovatore | Verdi; Mario del Monaco, Renata Tebaldi, Giulietta Simionato, Giorgio Tozzi, Alberto Erede | 3 |
| 1962 | Aïda | Verdi; Price, Vickers, Gorr, Merrill, Tozzi, Rome Opera House Orchestra and Chorus, Solti conducting | 7 |
| 1962 | Der fliegende Holländer | Wagner; George London, Leonie Rysanek, Giorgio Tozzi, Chorus and Orchestra of the Royal Opera House, Covent Garden, Antal Doráti | 4 |
| 1965 | Luisa Miller | Giuseppe Verdi; Anna Moffo, Carlo Bergonzi, Shirley Verrett, Cornell MacNeil, Giorgio Tozzi, Ezio Flagello, RCA Italiana Opera Orchestra, Fausto Cleva | 6 |
| 1987 | La bohème | Giacomo Puccini; Anna Moffo, Richard Tucker, Mary Costa, Robert Merrill, Giorgio Tozzi, Philip Maero, Rome Opera Orchestra and Chorus, Erich Leinsdorf | 4 |
| 1988 | La fanciulla del West | Puccini; Tebaldi, del Monaco, MacNeil, Tozzi, Orchestra e Coro dell’Accademia di Santa Cecilia, Roma, Franco Capuana | 2 |
| 1988 | La forza del destino | Giuseppe Verdi; Leontyne Price, Richard Tucker, Robert Merrill, Shirley Verrett, Giorgio Tozzi, Ezio Flagello, RCA Italiana Opera Orchestra and Chorus, Thomas Schippers | 2 |
| 1989 | Requiem / Quattro pezzi sacri | Verdi; Price, Elias, Björling, Tozzi, Singverein der Gesellschaft der Musikfreunde, Wien, Wiener Philharmoniker, Fritz Reiner | 3 |
| 1990 | Rigoletto | Giuseppe Verdi; Roberta Peters, Jussi Björling, Giorgio Tozzi, Rome Opera Orchestra & Chorus, Jonel Perlea | 1 |
| 1990 | Vanessa | Barber; Eleanor Steber, Nicolai Gedda, Rosalind Elias, Giorgio Tozzi, Regina Resnik, Dimitri Mitropoulos, Metropolitan Opera Orchestra & Chorus | 2 |
| 1996 | La forza del destino | Verdi; Zinka Milanov, Giuseppe Di Stefano, Leonard Warren, Giorgio Tozzi, Orchestra e Coro dell’Accademia di Santa Cecilia, Roma, Fernando Previtali | 1 |
| 1996 | Turandot | Giacomo Puccini; Birgit Nilsson, Renata Tebaldi, Jussi Björling, Giorgio Tozzi, Rome Opera Orchestra and Chorus, Erich Leinsdorf | 4 |
| 2006 | Vanessa | Barber; Steber, Elias, Malaniuk, Gedda, Tozzi, Dimitri Mitropoulos | 1 |
| 2016 | Romeo and Juliet | Berlioz; Charles Munch, Boston Symphony Orchestra, Rosalind Elias, Cesare Valletti, Giorgio Tozzi, New England Conservatory Chorus | 1 |
