| # | Title | Artist | Length |
|---|
| 1 | Astronomy Domine | Pink Floyd | 4:12 |
| 2 | Lucifer Sam | Pink Floyd | 3:07 |
| 3 | Matilda Mother- recording engineer:
- Peter Bown (on 1967-02-21)
- engineer:
- Peter Bown (in 1967)
- producer and phonographic copyright (℗) by:
- Norman Smith (in 1967)
- bass guitar and background vocals:
- Roger Waters (on 1967-02-21)
- drums (drum set):
- Nicky Mason (on 1967-02-21)
- electric guitar:
- Syd Barrett (on 1967-02-21)
- farfisa and Hammond organ:
- Rick Wright (on 1967-02-21)
- lead vocals:
- Syd Barrett (on 1967-02-21) and Rick Wright (on 1967-02-21)
- phonographic copyright (℗) by:
- EMI Records Ltd. (in 1997, in 2007)
- recorded at:
- Abbey Road Studios in St John's Wood, Westminster, London, England, United Kingdom (on 1967-02-21)
- recording of:
- Matilda Mother (on 1967-02-21)
- lyricist and composer:
- Syd Barrett
- publisher:
- Essex Music, Essex Music International, Essex Music, Inc., Magdalene Music, TRO-Essex Music, Inc., TRO-Hampshire House Publishing Corp. and Westminster Music Ltd.
| Pink Floyd | 3:08 |
| 4 | Flaming | Pink Floyd | 2:46 |
| 5 | Pow R. Toc H.- recording engineer:
- Peter Bown (from 1967-03 until 1967-04)
- engineer:
- Peter Bown (in 1967)
- producer and phonographic copyright (℗) by:
- Norman Smith (in 1967)
- acoustic guitar and electric guitar and other vocals [vocal percussion]:
- Syd Barrett (from 1967-03 until 1967-04)
- bass guitar and other vocals [screams]:
- Roger Waters (from 1967-03 until 1967-04)
- drums (drum set) and percussion:
- Nicky Mason (from 1967-03 until 1967-04)
- farfisa, piano and additional other vocals [vocalizations]:
- Rick Wright (from 1967-03 until 1967-04)
- phonographic copyright (℗) by:
- EMI Records Ltd. (in 1997, in 2007)
- recorded at:
- Abbey Road Studios in St John's Wood, Westminster, London, England, United Kingdom (from 1967-03 until 1967-04)
- recording of:
- Pow R. Toc H. (from 1967-03 until 1967-04)
- composer:
- Syd Barrett, Nick Mason, Roger Waters and Richard Wright
- publisher:
- Essex Music, Essex Music International, Essex Music, Inc., Magdalene Music, TRO Essex Music Ltd., TRO-Essex Music, Inc., TRO-Hampshire House Publishing Corp. and Westminster Music Ltd.
| Pink Floyd | 4:26 |
| 6 | Take Up Thy Stethoscope and Walk | Pink Floyd | 3:07 |
| 7 | Interstellar Overdrive- recording of:
- Interstellar Overdrive
- composer:
- Syd Barrett, Nick Mason, Roger Waters and Richard Wright
- publisher:
- Essex, Essex Music, Essex Music International, Essex Music, Inc., Magdalene Music, TRO-Essex Music, Inc., TRO-Hampshire House Publishing Corp. and Westminster Music Ltd.
| Pink Floyd | 9:42 |
| 8 | The Gnome | Pink Floyd | 2:13 |
| 9 | Chapter 24 | Pink Floyd | 3:42 |
| 10 | Scarecrow | Pink Floyd | 2:11 |
| 11 | Bike- recording of:
- Bike
- lyricist and composer:
- Syd Barrett
- publisher:
- Essex, Essex Music, Essex Music International, Essex Music, Inc., Magdalene Music, Tro-Cromwell Music, Inc., TRO-Essex Music, Inc., TRO-Hampshire House Publishing Corp. and Westminster Music Ltd.
| Pink Floyd | 3:22 |
| 12 | Scream Thy Last Scream (1974 mix) | Pink Floyd | 4:41 |
| 13 | Vegetable Man (1974 mix) | Pink Floyd | 2:31 |
| 14 | Paint Box | Pink Floyd | 3:29 |
| 15 | No Title (1967‐09‐04) | Pink Floyd | 1:36 |
| 16 | Apples and Oranges | Pink Floyd | 3:06 |
| 17 | Remember a Day- recording of:
- Remember a Day
- lyricist and composer:
- Richard Wright
- publisher:
- Essex, Essex Music International, Essex Music International, Inc., Essex Music, Inc., Lupus Music Co. Ltd, Magdalene Music, TRO-Essex Music, Inc., TRO-Hampshire House Publishing Corp. and Westminster Music Ltd.
| Pink Floyd | 4:33 |
| 18 | Set the Controls for the Heart of the Sun | Pink Floyd | 5:28 |
| 19 | Corporal Clegg | Pink Floyd | 4:13 |
| 20 | Scarecrow (left channel, not OOPS) | Pink Floyd | 2:08 |
| 21 | Astronomy Domine (left channel, not OOPS) | Pink Floyd | 4:05 |