| # | Title | Length |
|---|
| 1 | The Promise | 5:03 |
| 2 | Love Is the Key | 4:55 |
| 3 | Biology | 3:57 |
| 4 | Miss You Bow Wow- video director:
- Paul Caslin
- live recording of:
- Miss You Bow Wow
- writer:
- Myra Antonia Boyle, Cheryl, Miranda Cooper, Lisa Cowling, Nadine Coyle, Sarah Harding, Brian Higgins, Owen Parker, Tim Powell, Nicola Roberts, Toby Scott and Kimberley Walsh
- publisher:
- EMI Music Publishing Ltd., Warner Chappell and Xenomania
| 5:13 |
| 5 | The Loving Kind | 3:58 |
| 6 | Waiting | 4:15 |
| 7 | Love Machine | 4:35 |
| 8 | Rolling Back the Rivers in Time | 4:32 |
| 9 | Untouchable | 6:53 |
| 10 | Sexy! No No No | 4:24 |
| 11 | Broken Strings | 4:18 |
| 12 | Love Is Pain | 4:14 |
| 13 | Call the Shots | 4:39 |
| 14 | Revolution in the Head | 5:50 |
| 15 | Sound of the Underground | 4:28 |
| 16 | Fix Me Up- video director:
- Paul Caslin
- live recording of:
- Fix Me Up
- lyricist:
- Reuben Bell, Nick Coler, Miranda Cooper, Kieran Jones, Tim Powell, Wardell Quezergue, Jason Resch and Jerry Strickland
- composer:
- Reuben Bell, Carla Marie, Nick Coler, Miranda Cooper, Brian Higgins, Kieran Jones, Tim Powell, Wardell Quezergue, Jason Resch and Jerry Strickland
- publisher:
- Warner Chappell and Xenomania
| 2:38 |
| 17 | Womanizer | 4:28 |
| 18 | Something Kinda Ooooh | 5:48 |
| 19 | Out of Control Tour Megamix- video director:
- Paul Caslin
- live medley including a recording of:
- Can’t Speak French
- writer:
- Carla Marie, Nick Coler, Miranda Cooper, Brian Higgins, Jody McClure and Tim Powell
- publisher:
- Warner Chappell
- live medley including a cover recording of:
- Jump (for My Love)
- writer:
- Stephen Mitchell, Marti Sharron and Gary Skardina
- publisher:
- Anidraks Music, ATV Music, Braintree Music, Copyright Control and Sony/ATV Songs LLC
- live medley including a recording of:
- No Good Advice
- writer:
- Nick Coler, Miranda Cooper, Lisa Cowling, Matt Gray, Brian Higgins, Shawn Lee, Lene, Tim Powell and Tim Elliott Larcombe
- live medley including a recording of:
- The Promise
- writer:
- Carla Marie Williams, Nick Coler, Miranda Cooper, Brian Higgins, Kieran Jones, Tim Powell and Jason Resch
- publisher:
- Warner Chappell and Xenomania
- live medley including a recording of:
- The Show
- lyricist and composer:
- Miranda Cooper, Lisa Cowling, Brian Higgins, Tim Powell and Jon Shave
- publisher:
- Warner Chappell and Xenomania
- live medley including a recording of:
- Wake Me Up
- writer:
- Miranda Cooper, Lisa Cowling, Brian Higgins, Shawn Lee, Yusra Maru'e, Tim Powell and Paul Woods
| 7:24 |
| 20 | The Promise (video) | 4:07 |
| 21 | The Loving Kind (video) | 3:58 |
| 22 | Untouchable (video) | 4:15 |
| 23 | Revolution in the Head (Cheryl cam) | 3:56 |
| 24 | Love Machine (Nicola cam) | 4:07 |
| 25 | Miss You Bow Wow (Sarah cam)- recording of:
- Miss You Bow Wow
- writer:
- Myra Antonia Boyle, Cheryl, Miranda Cooper, Lisa Cowling, Nadine Coyle, Sarah Harding, Brian Higgins, Owen Parker, Tim Powell, Nicola Roberts, Toby Scott and Kimberley Walsh
- publisher:
- EMI Music Publishing Ltd., Warner Chappell and Xenomania
| 3:21 |
| 26 | Sound of the Underground (Nadine cam) | 3:54 |
| 27 | Love Is the Key (Kimberley cam) | 4:18 |
| 28 | Womanizer (visuals) | 3:53 |
| 29 | Love Machine (visuals) | 4:09 |
| 30 | Love Is the Key (visuals) | 4:18 |
| 31 | Revolution in the Head (visuals) | 4:55 |
| 32 | Biology (visuals) | 3:29 |
| 33 | Out of Control Tour Interview | 8:26 |