| # | Title | Artist | Length |
|---|
| 1 | Theme from I Want to Live | Gerry Mulligan and The Jazz Combo | 6:54 |
| 2 | Black Nightgown | Gerry Mulligan and The Jazz Combo | 3:34 |
| 3 | Night Watch | Gerry Mulligan and The Jazz Combo | 3:54 |
| 4 | Frisco Club | Gerry Mulligan and The Jazz Combo | 4:43 |
| 5 | Barbara's Theme | Gerry Mulligan and The Jazz Combo | 4:38 |
| 6 | Life's a Funny Thing | Gerry Mulligan and The Jazz Combo | 5:12 |
| 7 | Main Title | Johnny Mandel and his Orchestra | 1:21 |
| 8 | Poker Game | Johnny Mandel and his Orchestra | 1:36 |
| 9 | San Diego Party | Johnny Mandel and his Orchestra | 4:08 |
| 10 | Henry Leaves | Johnny Mandel and his Orchestra | 1:39 |
| 11 | Stakeout | Johnny Mandel and his Orchestra | 4:02 |
| 12 | Barbara's Surrenders | Johnny Mandel and his Orchestra | 2:05 |
| 13 | Trio Convicted | Johnny Mandel and his Orchestra | 1:12 |
| 14 | Trip to Corona | Johnny Mandel and his Orchestra | 1:29 |
| 15 | Peg's Visit | Johnny Mandel and his Orchestra | 2:36 |
| 16 | Gas Chamber Unveiling | Johnny Mandel and his Orchestra | 1:03 |
| 17 | Nightmare Sequence | Johnny Mandel and his Orchestra | 1:08 |
| 18 | Preparations for Execution | Johnny Mandel and his Orchestra | 2:49 |
| 19 | Letter Writing Sequence | Johnny Mandel and his Orchestra | 1:25 |
| 20 | The Last Mile | Johnny Mandel and his Orchestra | 1:48 |
| 21 | Death Scene | Johnny Mandel and his Orchestra | 1:04 |
| 22 | End Title | Johnny Mandel and his Orchestra | 0:54 |