| # | Title | Artist | Length |
|---|
| 1 | Theme to St. Trinians | Girls Aloud | 4:31 |
| 2 | Trouble | Cast of St. Trinian’s | 3:34 |
| 3 | Oh My God | Mark Ronson feat. Lily Allen | 3:40 |
| 4 | Love Is in the Air | Rupert Everett & Colin Firth | 3:51 |
| 5 | Don't Give Up | Noisettes | 2:31 |
| 6 | Nine2Five | The Ordinary Boys vs. Lady Sovereign | 3:04 |
| 7 | If I Can't Dance | Sophie Ellis‐Bextor | 3:25 |
| 8 | Teenage Kicks | Remi Nicole | 2:28 |
| 9 | Sanctuary | Gabriella Cilmi | 3:30 |
| 10 | Love Is a Many Splendored Thing | The Four Aces | 3:00 |
| 11 | 3 Spoons of Suga | Sugababes | 3:52 |
| 12 | On My Way to Satisfaction | Girls Aloud | 4:06 |
| 13 | Defenders of Anarchy (The St. Trinian's School Song) | Cast of St. Trinian’s | 3:47 |
