| # | Title | Artist | Length |
|---|
| 1 | Soul Man | Sam & Dave | 2:57 |
| 2 | Thank You Pretty Baby | Brook Benton | 2:24 |
| 3 | Since You’ve Been Gone | Ramsey Lewis | 3:04 |
| 4 | I Got the Feeling | James Brown | 3:36 |
| 5 | Warm and Tender | Percy Sledge | 3:14 |
| 6 | Dance With Me | The Drifters | 2:25 |
| 7 | Rainy Night in Georgia | Brook Benton | 3:58 |
| 8 | Up Tight | Ramsey Lewis | 3:00 |
| 9 | So Sad the Song | Gladys Knight | 3:58 |
| 10 | Papa’s Got a Brand New Bag | James Brown | 2:13 |
| 11 | Soul Sister, Brown Sugar | Sam & Dave | 2:36 |
| 12 | Tighten Up | Archie Bell & the Drells | 2:49 |
| 13 | The in Crowd | Dobie Gray | 2:53 |
| 14 | Sex Machine | James Brown | 4:20 |
| 15 | I Thank You | Sam & Dave | 2:54 |
| 16 | Oh No Not My Baby | Maxine Brown | 2:40 |
| 17 | Fools Rush In | Brook Benton | 2:18 |
| 18 | Up on the Roof | The Drifters | 2:35 |
| 19 | Every Beat of My Heart | Gladys Knight | 2:05 |
| 20 | Spanish Harlem | Ben E. King | 3:00 |
| 21 | So Many Ways | Brook Benton | 2:31 |
| 22 | When a Man Loves a Woman- producer:
- Marlin Greene and Quin Ivy
- double bass:
- Albert Lowe Jr. (on 1966-02-17)
- drums (drum set):
- Roger Hawkins (on 1966-02-17)
- farfisa [farfisa organ]:
- Spooner Oldham (on 1966-02-17)
- guitar:
- Marlin Greene (on 1966-02-17)
- vocals:
- Percy Sledge (on 1966-02-17)
- phonographic copyright (℗) by:
- HHO Ltd., WEA International Inc. (, in 1966) and Atlantic Recording Corporation (in 1966)
- recorded at:
- Norala Studio in Sheffield, Alabama, United States (on 1966-02-17)
- part of:
- Rolling Stone: 500 Greatest Songs of All Time (number: 54) and Rock and Roll Hall of Fame – 500 Songs That Shaped Rock
- recording of:
- When a Man Loves a Woman (on 1966-02-17)
- writer:
- Calvin Lewis and Andrew Wright
- publisher:
- Mijac Music, Warner Chappell, Warner Chappell Music, Warner Chappell Music Ltd., Warner Chappell North America, Warner/Chappell, Pronto Music, Inc. (from 1966 to present), Quinvy Music Publishing Company, Inc. (from 1966 to present), Warner–Tamerlane Publishing Corp. (from 1966 to present), Pronto (in 1972) and Quinvy (in 1972)
| Percy Sledge | 2:59 |
| 23 | On Broadway- recorded in:
- New York, New York, United States (on 1963-01-22)
- producer:
- Leiber and Stoller
- bass:
- Russ Saunders (on 1963-01-22)
- drums (drum set) [drums]:
- Gary Chester (on 1963-01-22)
- guitar:
- Everett Barksdale (on 1963-01-22), Bill Suyker (on 1963-01-22), Billy Davis (on 1963-01-22) and Billy Butler (on 1963-01-22)
- percussion:
- Martin Grupp (on 1963-01-22), Phil Kraus (on 1963-01-22) and Nick Rodriquez (on 1963-01-22)
- trumpet:
- Joe Newman (on 1963-01-22) and Ernie Royal (on 1963-01-22)
- background vocals:
- vocal group (on 1963-01-22)
- baritone vocals:
- Eugene Pearson (on 1963-01-22)
- bass vocals:
- Tommy Evans (on 1963-01-22)
- lead vocals:
- Rudy Lewis (on 1963-01-22)
- tenor vocals:
- Charlie Thomas (on 1963-01-22)
- vocals:
- Doris Troy (on 1963-01-22), Dee Dee Warwick (on 1963-01-22) and Dionne Warwick (on 1963-01-22)
- phonographic copyright (℗) by:
- Atlantic Recording Corporation (in 1988) and WEA International Inc. (in 1998)
- recording of:
- On Broadway (on 1963-01-22)
- additional writer:
- Jerry Leiber and Mike Stoller
- writer:
- Barry Mann and Cynthia Weil
- publisher:
- Colgems-EMI Music Inc., Screen Gems‐Col, Screen Gems–EMI Music Ltd., Screen Gems–EMI Music, Inc., イーエムアイ音楽出版 フジパシフィック事業部 (until 2021-06-30) and ソニー・ミュージックパブリッシング フジパシフィック事業部 (from 2021-07-01 to present)
- version of:
- On Broadway
| The Drifters | 2:57 |
| 24 | Please, Please, Please | James Brown | 2:12 |
| 25 | High Heel Sneakers | Ramsey Lewis | 2:38 |
