| # | Title | Artist | Length |
|---|
| 1 | Rock Me | Muddy Waters | 3:17 |
| 2 | I Rule My Den | John Lee Hooker | 2:47 |
| 3 | Shotgun Blues | Lightnin’ Hopkins | 2:42 |
| 4 | Airplane Blues | Sonny Terry & Brownie McGhee | 2:50 |
| 5 | Key to the Highway- producer:
- Don Nix and Leon Russell
- mixer:
- John Fry
- drums (drum set):
- Charles Blackwell and Charles Myers
- electric bass guitar:
- Donald “Duck” Dunn
- electric guitar and lead vocals:
- Freddie King
- guitar:
- Don Preston and Leon Russell
- organ:
- Jon Gallie
- piano:
- Leon Russell
- background vocals:
- Joey Cooper, Claudia Lennear, Kathl McDonald and Don Preston
- recorded at:
- Chess Studios in Chicago, Illinois, United States (in 1970-10)
- mixed at:
- Ardent Studios in Memphis, Tennessee, United States (in 1971-01)
- cover recording of:
- Key to the Highway
- writer:
- Big Bill Broonzy and Charles Segar
- publisher:
- Duchess Music Corporation, MCA Duchess Music Corporation, Songs of Universal, Inc., Universal Duchess Music Corp. and Wabash Music Co.
| Freddie King | 3:27 |
| 6 | Baby Please Don't Go | Mississippi Fred McDowell | 3:08 |
| 7 | Juke | George “Harmonica” Smith | 3:15 |
| 8 | Bad Luck Blues | Jimmy Rogers | 2:57 |
| 9 | Call It Stormy Monday but Tuesday Is Just as Bad | T‐Bone Walker | 3:04 |
| 10 | New Arrival | Guitar Slim & His Playboys | 2:34 |
| 11 | Between Midnight & Day | Son House | 6:25 |
| 12 | Boogie Woogie Stomp | Albert Ammons | 3:39 |
| 13 | Honky Tonk Train Blues | Meade Lux Lewis | 4:17 |
| 14 | All This Piano Boogie | Memphis Slim | 1:27 |
| 15 | Cow Cow Boogie | Ella Mae Morse | 3:15 |
| 16 | Jumpin' Tonight | Big Joe Turner | 2:24 |
| 17 | He's a Real Gone Guy | Nellie Lutcher | 3:03 |
| 18 | Blues Before Dawn | Pee Wee Crayton | 2:00 |
| 19 | Trouble in Mind | Amos Milburn | 2:36 |
| 20 | The Blues Ain't Nothin' but a Woman Cryin' for Her Man | Dinah Washington | 3:47 |
| 21 | San Francisco Blues | Floyd Dixon | 3:03 |
| 22 | Gin House Blues | Nina Simone | 3:03 |